In this work, ten different samples were investigated for pre-lithiation techniques, namely 100GR, baseline, CM10, CM20, CM30, CM40, EM1C, EM2C, EM3C, and EM4C, respectively (Table 1 ). Among them, 100GR was represented for full-cell consisting of 100 wt.% graphite: 1.5 wt.% CMC: 2.5 wt.% SBR as anode and NMC622 as cathode. The other samples included 80 wt.% graphite: 20 wt.% SiO₂/C: 1 wt.% C65: 1.5 wt.% CMC: 2.5 wt.% SBR as anode and NMC622 as cathode. In detail, the 100GR and baseline were named full-cells without prelithiated anode. In contrast, the CM samples mean the anode using the direct contact method. For instance, “CM10” indicates that full-cell was assembled using the anode contacted with lithium foil for 10 minutes. Meanwhile, the EM samples describe the anode using the electrochemical method, whereas the anode was assembled in half-cell and cycled in several cycles. For example, “EM1C” indicates that the full-cell was assembled by the anode using an electrochemical technique and activated by one cycle.